You can use PRIMARY KEY constraints to enforce entity integrity as well as referential integrity. A PRIMARY KEY constraint ensures that no duplicate values are entered, that NULL values are not allowed, and that an index is created to enhance performance.
To create a PRIMARY KEY constraint(For details, search for "constraints" in SQL Enterprise Manager Help.)
OR
For example:
ALTER TABLE authors ADD CONSTRAINT UPKCL_auidind PRIMARY KEY CLUSTERED (au_id)
adds a PRIMARY KEY constraint on the au_id column. Note that this table already has a primary key defined on it.
(For details, see the CREATE TABLE and ALTER TABLE statements in the Microsoft SQL Server Transact-SQL Reference.)