If a user has Send As permission on a mailbox, that user can send a message with the return address of the mailbox so it appears that the message was sent by the mailbox owner. Send As permission can be granted to user accounts only with the Administrator program.
Note Send As permission overrides Send On Behalf Of permission. For example, if a user has both Send As and Send On Behalf Of permissions for another user, any message sent in the other user's name has that user's name as the return address.
To grant Send As permission
If the Permissions tab is not available, choose Options from the Tools menu, select the Permissions tab, and then select the Show Permissions page for all objects and Display rights for roles on Permissions page check boxes.